Fill a deep fryer or a deep-sided pot halfway full with oil and heat to 375°F.
While the oil is heating, combine the chocolate pudding mix, dark chocolate, instant coffee, and cayenne pepper in a small bowl.
Place the French fries into the hot oil and cook until golden brown. Place the fries in a large bowl and toss with about 1/3 of the chocolate mixture. Repeat 2 more times, or until fries are fully coated.
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